A treatise on dynamics of a particle - download pdf or read online

By Edward John Routh

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Perkin I , 1974, 1266. 118 C. H. DePuy and A. L. Schultz, J. Org. , 1974, 39, 878. laa Saturated Fluorocarbons, Fluorocarbon Hydrides, and Fluorocarbon Halides 27 Similar work, reported earlier,129 has been carried out in order to probe the mechanism of base-initiated (EtONa-EtOH at 25 "C) dehydrohalogenation of the a-chloro-compounds PhCHCl-CF2X (X = Cl or F). e. CF2CI-HCI) (using rn- and p-Me and rn- andp-C1 substituents); (v) the differences in the effects of a CFzCl and a CF3 substituent on an adjacent CH group or carbanionic site in terms of acidity and stability, respectively, should be small; and (vi) the activation energy for hydrogen isotope exchange in PhCTCl CF3 is ca.

C. W u and A. S. Rodgers, Internat. J . Chem. Kinetics, 1973, 5 , 1001. @ E . 4 . Wu and A. S. Rodgers, J. Phys. , 1974, 78, 2315. g. g. r. 184 The a-fluorine hyperfine interaction decreases and the ,8-fluorine interaction increases as a-fluorine atoms are progressively replaced by trifluoromethyl groups, a behaviour consistent with increasing deviation from planarity as the number of a-fluorines increases (cf. p. 25); aPvalues found in C2F5' and (CF&CF* are almost exactly the same as those in eCHF2 and *CH2F, and the deviation from planarity 8 (the angle between the plane perpendicular to the axis of the odd-electron orbital and the C--C or C-F, bond) in the perfluoro-radicals is estimated to be 8".

H. Hellberg and J. Massonne, Ger. P. 1 668 346/1973 (Chem. , 1973,78, 147 334f). 2 0 4 K. Maeda, M. Sano, and M. Kawagishi, Japan. Kokai 73 72 105 (Chem. , 1974, 80, 59 424w). 2 0 5 A. Posta, 0. Paleta, and J. Voves, Czech. P. 153 681/1974 (Chem. , 1974, 81, 169 101s). 2 0 6 J. C. Clark, R. W. Goulding, and A. J. Palmer, Radiopharm. Label. Compounds Proc. , 1973,1,411 (Chem. , 1974,81, 169 02%). 2 0 7 G. P. Gambaretto, Chimica e Industria, 1973, 55, 18 (Chem. , 1973,78, 123 903q). L. S. Boguslavskaya, K.

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A treatise on dynamics of a particle by Edward John Routh

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